I'm hoping to get better battery life while boosting
It's hard to say. Maybe, but is it significant? Your slick
mods do look to be a hassle for batt changes. To me the only advantage to boosting would be to have an in-
mod charger. I guess they may be safer (no stack). But the TI adjustable regs (I can get 8 UCC283-ADJ for the price of one booster) can handle more watts and are much smaller. If you are a Joye atty user the booster's "Up to 12 W Output Power" means 5V is pushing it to the max. Would probably be best to stay a bit below that.
Mamu's new
mod uses the LDO just for that reason. She wanted the 5.4V that the booster could not provide.
About those caps they can make for a very tidy build. Here's tinear's work.