steam is water in its gassiest form.steam is invisible.
vapor is very tiny visible water droplets.(think fog)
when steam(invisible) loses temperature below boiling it
it condenses into water droplets.(visible)
conversely when water heats up before it turns to steam it produces vapor.
a lot of water is used in the production of PG and some less in VG.
a good amount of water becomes bonded to other molecules creating
more complex molecules. hence 98% pure is accurate.
however once heating starts a lot of the water molecules will break
their bonds from the more complex molecules creating first vapor,
then steam,then back to vapor.
so what we actually can see is the water vapor. the other stuff is there,
we just can't see it. if we could see it my vapor should be dark brown.
the process works both ways. you do not have to boil it to get vapor.
you can if you like but its not necessary.
VG gives off better vapor because it makes the vapor less opaque than PG.
can't recall but i think VG may be thicker than PG.
remember water boils at 212 degrees F. that's a lot lower than PG or VG.
so chemical reactions will affect the water bonded to other molecules first.

regards
mike
I really don't mean to be argumentative here, but you just don't seem to understand the processes at work here. I'm not saying this to be prudish, but please do do some research on vapor and exactly what it is.
Yes, steam is water in a gaseous phase. Absolutely... meaning that it too is vapor... Because vapor is just that... a substance in a gaseous phase. It has NOTHING to do with being visible. ANY vapor is invisible. Vapor is NOT defined by being visible or not. When you see a "cloud" of any vapor, it's only because that vapor is condensing back into liquid droplets. It's those droplets that are now visible.
As water evaporates off the ocean it forms steam... Yes, it's water vapor, but also steam... because again, the pure definition of steam simple means water vapor... or the vapor that is formed when water turns to a gaseous state. That steam rises in the air and is cooled.... As it does so it begins to condense again... Making small water droplets... It's these droplets that are visible and therefore become clouds.
Again, and I can't stress this enough... visibility has NOTHING to do with rather something is a vapor, or steam or anything... Visibility is only determined by how much vapor has condensed back into liquid... these droplets of liquid are suspended in air and are visible... Vapor is NOT visible... in fact, once it becomes visible it means it has condensed and is no longer vapor...
Ever busted an old mercury vapor fluorescent light? How much "vapor" did you see? None... Because it's not visible...
The ONLY thing that makes a vapor visible is the fact that it will have a different refractive index, meaning it will bend light differently so distort objects behind it. This is the only way "vapor" can be seen. Again it all comes down to what I said earlier. You are confused on the definitions of steam, vapor and liquid. Again, vapor is NOT the visible water droplets... Vapor is the gaseous form of any substance... droplets be them water or ANY other liquid are just that, droplets of liquid... They are NO LONGER VAPOR... I know I'm repeating myself, but I just can't stress this point enough.
And water can not produce vapor before it turns to steam... The MOMENT water turns into vapor it is steam... Again, pure definition states that steam is just water vapor.
I don't want to go into chemistry here (and I'll be honest that's not my strong point) but regardless of rather water is used in the production of PG or VG it doesn't make any difference... When the chemical structure is changed it's changed.
But your statement that heating will "break the bonds of the water molecules creating vapor" just isn't true... One the PG is formed, even if water is used as a catalyst (I'm not so sure that it is) once PG is formed there are no water molecules there. Again chemistry isn't my strong point so I won't even try to explain extensively, but when substances react to create new substances it's not like the molecules of these substances stay in their perfect structure and just attach to each other... Not generally speaking... They react to form NEW molecules...
And of course your vapor won't be dark brown... Why? Because of exactly what I mentioned earlier about the distilling process... Think about this for a minute...
If I take a pot of water and color it with green food coloring... Then I run that green water through a still what am I doing? I'm boiling the water to form vapor... which then goes into a tube where it's cooled... that vapor then condenses and forms back into water which comes out the other end.... Is the water that comes out the other end green? Of course not! That's the whole point of the distilling process... The pigments in the dye are going to be left behind... Along with anything else that has a boiling point higher than water! What comes out the other side is pure water... plain and simple... (again aside from anything with a boiling point lower than water itself...)
VG gives off better vapor than PG because it makes it less opaque? I'm not sure I follow you there... I swore I wasn't going to get into this, LOL, but here goes anyway...
An azeotrope is when two or more substances form a bond that cannot be separated by distilling... So in my earlier example, water and ethanol form an azeotrope at 95% (roughly if memory serves me). This means you can never distill ethanol to be higher that 95% pure... Because when two or more substances form an azeotrope, they "change" the boiling point of the two or more substances... It's kinda like they form one new substance that has a different boiling point.
PG and VG form an azeotrope that has a different boiling point than either one of them individually. If they didn't, then these mixes wouldn't work as you would just get one of the substances vaporizing and leaving the other behind to gunk up the coil.
But... Because VG has a higher boiling point than PG, the more VG in the mixture the higher the overall boiling point of the VG and PG become. When this mixture is vaporized, it immediately starts to cool... which means it also starts to condense....
Now remember... it's this condensation that we "see"... NOT the vapor....
So since more VG raises the boiling point, that means that it condenses much quicker.... So the more VG we put in our juice, the faster it condenses... which means the more "clouds" we can see... There's more to it than that... but that's the easiest way I can explain it.