Glad to see you made the jump. Like Jerms said, have some fun with it! Keep us posted and ask questions when in doubt. The process is really pretty simple and the rewards are satisfying.
I dove in tonight too. I have half-pint mason jars steeping of McClelland's Blending Perique, McClelland's Blending Oriental, Mac Baren HH Acadian Perique, Brigham Legend Series Acadian Blend, and New York Pipe Club Bledsoe's Island VaPerOriental. 1/2 ounce each in 120ml of pure PG.
Right out of the freshly opened tins, the ones whose smell intrigued me the most were the Mac Baren HH Acadian Perique and the NYPC Bledsoe's Island VaPerOriental. The Mac Baren had a deep, rich, smokey scent. The Dark Fired Kentucky in it really popped. The NYPC had a nice, soft, slightly toasted natural tobacco smell.
It was interesting to see how each behaved once they were soaking, like how much volume they took up or how they stayed (or not) suspended in the PG.
Now, just to wait a month, which is going to be torture. My single varietals should be here tomorrow too, and I'm going to get a couple of them started this weekend. Now, I'm kicking back and relaxing with some Smug Juice B(r)anded as a reward for all my hard work.