On a dual 18650 mod in parallel the battery voltage begins at 4.2 volts (at full charge). On a dual 18650 mod in series the volts are double 4.2x2= 8.4 volts.
Batteries will hang in the 3.7v range but always begin at 4.2v and you will get so many puffs at that level first. So you measure at the highest volt rating for safety reasons. So for safety in a series mod, one must count double voltage on a parallel do NOT double amp rating, only capacity (mah) which is run time.
Parallel: 2- 20A CDR 2500mah batteries should be looked at as 30A CDR MAX with 5000mah with start voltage of 4.2
Series: 2- 20A CDR 2500mah batteries should be looked at as 20A CDR MAX with 2500mah with start voltage of 8.4
I recommend going to youtube and watching Mooch episode 1 and 2, it will explain everything very simply, much easier than reading/writing it. He is the battery guru we all listen to for safety and such.