The R2 ends at the positive leg of the small capacitor, and before it is that little black box with the etching 0W11.
What do you mean, which is input/output?
If you mean by charge, the center is the mini usb and the far left is the USB out,
Strange ... i dont see how you can vape from that point as the only dc path is through the 100 ohm resistor. Are you sure that point doesn't connect to somewhere else, on the other side perhaps?
What markings are on the left most chip? I think that one is the voltage converter; need to confirm.