I think this is a good question because the reason I prefer it is unknown at this stage. Without analysis of what is actually in the vapour, it's difficult to know why the particular combination of natural chemicals is so satisfying. WTA definitely sounds like it's closer to actual tobacco, but I'd need to compare them to give my opinion. I do think that once you start entering the realm of that kind of extraction/purification it's an additional process being carried out by unknown persons (i.e. an additional point where contamination could take place) and may not even include the ingredient/s I find so satisfying. I will try it though and feed back.
All I do know is it 'feels' like smoke in the lungs. It bites, like smoke does, but without stinging the throat on the way down. Some less reputable e-liquids I've tried have too much throat hit - much more than actual smoking in fact. It is almost like my body recognises that it's tobacco (I've smoked for nearly 30 years, since my pre-teens).
Back in the 80's I took part in a 3-month long Phillip Morris R&D trial of smokeless cigarettes. They looked just like regular cigarettes and even had real tobacco inside but that tobacco was heated by a catalytic pellet producing a wispy sort of vapor. The tobacco never burnt, scorched or was ever even discolored by the heating process. I didn't like them, the flavor was anemic and they had near zero throat hit.
Have you tried NETs? If not you might try Naturally-Extracted-Tobacco.com's Sun-Cured Turkish or Organic Spirit NETs are what brought me to vaping, nothing else comes close for providing a real tobacco experience. I make my own, ECF has a sub-forum for home extractors Liquid Extraction From Tobacco
If anyone reading this thread has resources to actually examine tobacco vapour (!), that would be great to discuss! There are lots of existing discussions around smoking tobacco vs e-cigs, but not comparing tobacco vapour to e-cig vapour.
NETs and the vapor they produce have been subjected to comprehensive scientific lab analysis, the results could be somewhat comparable to what you're doing, here's a link in case you're interested; IJERPH | Free Full-Text | Nicotine Levels and Presence of Selected Tobacco-Derived Toxins in Tobacco Flavoured Electronic Cigarette Refill Liquids | HTML and Dr. Farsalinos' view on the results of these tests; A new study verifies that e-cigarettes are orders of magnitude safer than tobacco cigarettes