OK, so I have been talking with a guy who is intimate with the type of instrument I used.
Here is what he said:
(I believe in full disclosure)
"I've skimmed over your tests.. So these comments are just first pass. Probably not what you want to hear, but... I don't think your restore will prove to be accurate, the good news is I think you were measuring
acetaldehyde and formaldehyde (and other compounds)
I spent decades working with the technology you used to measure. I don't know Extech, but I know the technology.
In combustion or reaction by product monitoring, I always focused on two areas first.
1) Representative sample. Is there a reaction that can change concentration of the analyte during sample gathering, conditioning (if any), transport and analysis. Example CO continues to oxidize post combustion, you can lose 10x or more of the CO (v/v) if you don't measure at or near combustion or reaction temperature.. H2O condenses, etc. I would have to refresh my understanding of CH2O to see how cooling of the sample affects it.
-- At this point I would ignore this issue. I think there is a bigger issue
2) What is the real LOQ (limit of quantification) for the measuring device. I looked briefly at the Extech unit, it is an electrochemical sensor. The biggest problem with electrochemical CH2O measurement is usually cross sensitivity to other aldehydes hydrocarbons, VOC's , etc .. They state 50% for ethanol and methanol for example. So if you had 1ppm of ethanol or methanol and 0ppm CH2O, it would read 0.5ppm CH2O. They don't state
acetaldehyde
I would be very interested in acetaldehyde cross interference. I suspect the cross sensitivity is close to 1:1. If so you were measuring formaldehyde + acetaldehyde + other VOC's
I don't know the PG/VG heat reaction by-products. I'm sure there is a list somewhere. I would ask Extech for their complete cross interference list.. Then if you can find out what else is in heat reacted PG/VG , you can add or subtract the interfering compounds.
You can get a repeatable measurement without accuracy. If the CH2O and VOC's repeat, the displayed CH2O will repeat. But the VOC's and
acetaldehyde might be a big part of the CH2O reading.
This is not a bad thing. If you were measuring formaldehyde and acetaldehyde, the numbers are even safer."
So...... I am going to email the
manufacturer of the sensor and ask them point blank if there is a cross interference with acetaldehyde or other aldehydes
, as its not listed in their documentation if there is.
If there is, then everything I did is invalid, and merely represents (more/less) total aldehydes.