There's always a variation in oxygen content with all of the oxide species being present depending on how many millimicrons deep one measures. The oxygen diffusion rate and the solubility of oxygen in metallic titanium are such that eventually as one goes deeper into the substrate there will be a noticeable tendency for the alpha (hexagonal close packed crystal structure) to be more and more stabilized and somewhat more brittle than the titanium metal with low oxygen content with no oxide as such present at all. This is all metallurgical gobbldygook for non metallurgists but the bottom line is that nothing bad happens with titanium in normal vaping and it provides an excellent totally safe vape in my opinion and the opinion of many others who use it regularly.
Duane
Duane, since you're one of the most scientifically adept posters on ECF (especially in materials science), I want to ask a few questions. You may or may not have answered some of these already in this mammoth thread, but I feel it would be nice to have some of your knowledge condensed.
1) With your Ti builds, do you space or use contact coils?
2) Do you pulse before wicking? If so, how hot?
3) Do you believe there is any transfer of nanoparticles into the vapor stream (whether it be TiO2 or some other material) under normal vaping conditions?
4) Just how adherent is TiO2 to the surface? Do different temperature levels affect the "strength" of the oxide on the surface (i.e., make it thicker, weaker, stronger, etc.). I realize high heat will make it flake off, but I am talking temperatures in the "vaping range." In other words, will there be any difference in the TiO2 layer at room temp and, say, at 500F?
5) If the surface becomes noticeably oxidated (white flaking powder we can see with the naked eye) is there any "recovery" from that (e.g. a wash)? Will the metal remain compromised after that?
6) What's your overall opinion of the various grades of stainless steel as coiling material? If you had to pick a grade that is the most heat resistant, oxidation resistant and chemically resistant, which would it be? Are any of the stainless steels safe to "dry burn" in our application without significantly compromising them?
I am not a lazy person and have tried to research this on my own, but the literature on Titanium is usually highly specialized for very specific uses. I am sure my questions are elementary for titanium engineers (or metallurgists in general). It would be like finding a technical paper from a mathematician trying to solve some problem in number theory where the author explains in the preface of his paper what addition and subtraction are. That type of thing doesn't happen. It is assumed the reader is an expert.
And Wikipedia isn't much help, either. It is a little too basic.
EDIT: I did find
this paper, which details some of the oxidation properties of CP Titanium in a furnace at temps from 20C all the way up to over 1000C. A TL;DR from an expert would be great. They talk about anatase and rutile formation quite a bit, for example.