Titanium wire, vaping and safety

Status
Not open for further replies.

druckle

Ultra Member
ECF Veteran
Verified Member
Sep 20, 2013
1,149
2,193
Scottsdale, Arizona, USA
I could definitely imagine Ti would be a good fit, as long as one was careful to keep the coil juiced at all times. Starting resistances are no lower than many Kanthal coils, and the resistance rise is not vast but enough to give a nice variable wattage curve when voltage is held constant.

A Ti 0.50Ω coil on a 4V battery would be firing at 32W at the start of the vape, then by the time the coil reaches 200°C / 392°F it will be at 0.815Ω and firing at 19W.

Pretty good idea I'd say, for those who like mechs.

Just so long as the coil never goes dry else it will, almost literally, be toast :)
Let's make this thread the one that converts the whole vaping world to Titanium coils....of course I'm vastly prejudiced but I really can't think of anything I would rate as a negative for titanium in coil performance and I can think of a whole lot of things I would rate as positives. I'm only 3.1% kidding.:)
 

xpen

Super Member
ECF Veteran
Jun 18, 2012
834
1,274
Italy
Why? I know that the topic of this (very very interesting) thread is about titanium wire and safety, but I do not get why you relate titanium coils in mech mods to oxides or exploding batteries.

To be honest I tried it myself a while ago. Just a simple 8 wrap contact coil of 0.34mm grade1 Ti (pre-torched to gold). It came out at 0.42 ohm at room temp, but when vaping the coil resistance steeply rises to 0.7 ohm (within a second). As long as you take care that your battery can handle such resistances there is no problem with that (just like with any build on a mech mod).

Any possible health advantage of Ti as discussed in this thread would be as valid for mech mods as they would be for regulated or temp limited mods. The only added risk I could think of is a dry hit on a mech mod, which might cause some additional oxidation of the wire. Don't know.. I guess it needs to be an extremely bad dry hit to get the dull grayish oxide layer in a single draw, I don't think this is possible. Anyway, the atty with Ti coil that I used on a mech mod never gives me a dry hit.

But a very interesting advantage of Ti coils, and that is why I tried it, is that Ti allows for coil resistances that suit both temp limiting devices as well as mech mods. This allows you to swap your atties between devices without rebuilding. My tests worked out quite well. I got a perfect vape on the mech mod and on my SX Mini, with the SX Mini being able to detect a dry wick and prevent scorching it.
My main concern there was about Ni200, specifically the softness of the wire.
To achieve even a meager 0.2 ohm resistance you'll need a lot of wire, and the chances of a wrap - or five - shorting out is quite high IMO.
Ti should be better for that purpose, less wire and much more robust at that, even though I wouldn't recommend either wire with mechs.
 

Cmoke

Senior Member
ECF Veteran
Verified Member
Feb 24, 2014
174
436
Mokum, NL, Europe
My main concern there was about Ni200, specifically the softness of the wire.
To achieve even a meager 0.2 ohm resistance you'll need a lot of wire, and the chances of a wrap - or five - shorting out is quite high IMO.
Ti should be better for that purpose, less wire and much more robust at that, even though I wouldn't recommend either wire with mechs.

Agreed, I wouldn't recommend it either on mechs or non-temp-controlled mods in general. But recommending something or doing it yourself are two different things ;)
 

awsum140

Resting In Peace
ECF Veteran
Verified Member
Jun 12, 2012
9,855
46,386
Sitting down, facing forward.
I don't know about that. I'm using a Fogger V6 with Ni200 coils. 13 wraps of 30 gauge Ni200 on a ~3mm mandrel. The net resistance of both coils is .13 ohms. No problems with touching wraps/shorts at all. I don't think I could stuff those coils into a smaller chimney though and if I did it would be a real PITA.

I am certainly not advocating use of Ni200 in mechs, and from my experience with metallic tastes from it, not advocating it in much of anything, really.
 

mrmonday

Senior Member
ECF Veteran
Feb 19, 2014
145
56
Carmel, California
Snowwolf 200w or Evic VT for titanium builds on an RDA?
Coming from mech mods I almost exclusively use drippers so i want to know which of these devices would work best with an RDA with a titanium build. I had the snowwolf on preorder but I didn't realize that it doesn't auto detect titanium wire which means that I would have to dial it down about 80 degrees to use titanium wire. The evic vt on the other hand does have a titanium setting but I don't like how it is more limited in its capabilities with kanthal and I don't like how its battery is non removable. My question is will the snowwolf pass a cotton burn test when using a titanium macro build on a dripper? It bothers me that I can't update the snowwolf with usb because they will surely release a titanium auto detect feature in the future.
 

tchavei

Vaping Master
ECF Veteran
Verified Member
Jul 15, 2014
4,765
8,710
Portugal
Both devices are unreleased at this moment so you won't get any personal experience but rather opinions / speculation.

I'm so used to the dna board (nickel) that I don't even recognize the offset. For me, my best vape for liquid x is 185C (365f) and for liquid y it's 180C (356f).

I don't really care that in reality the coil is being heated to 230C (446f) or 225C (437f) as long as it doesn't scorch the wick, produces dry hits or drives the actual temperature above 500f-600f

Once you free yourself of the numbers, choose the mod that has the features you like best :)

Regards
Tony

Sent from my keyboard through my phone or something like that.
 
Last edited:

mrmonday

Senior Member
ECF Veteran
Feb 19, 2014
145
56
Carmel, California
Both devices are unreleased at this moment so you won't get any personal experience but rather opinions / speculation.

I'm so used to the dna board (nickel) that I don't even recognize the offset. For me, my best vape for liquid x is 185C (365f) and for liquid y it's 180C (356f).

I don't really care that in reality the coil is being heated to 230C (446f) or 225C (437f) as long as it doesn't scorch the wick, produces dry hits or drives the actual temperature above 500f-600f

Once you free yourself of the numbers, choose the mod that has the features you like best :)

Regards
Tony

Sent from my keyboard through my phone or something like that.
Thanks, this is exactly what I was looking for. You can still do a dry burn test with titanium in your dna40 with no singe?
 

TheBloke

Ultra Member
Verified Member
Mar 30, 2015
2,800
3,549
45
Brighton, UK
@mrmonday thanks for your PM, I was in the process of replying last night when I fell asleep. My first response was to direct you to this thread so glad you're here.

This is what I was going on to say. I think this is good for general discussion, because it raises a point I wanted to discuss with @tchavei and other Titanium veterans:

The basic principle is that TC mods calculate the temperature by monitoring the rise in resistance of the coil. They do this with the following formula:

ΔT = ST + (Δρ / α * ρ0)
Where:
ST : Starting temperature
ΔT : Change of temperature
Δρ : Change of the resistivity
α : Temperature Coefficient of Resistance (TCR)
ρ0 : Original resistivity


The Temperature Coefficient of Resistance (TCR) is the key number. For Ni200, it's around 0.0062. For Titanium, it's 0.0035.

So let's say you start with a Titanium coil reading 0.40Ω. You vape it on a normal TC mod, that is expecting Ni200. The mod sees its resistance is now 0.673Ω. It calculates the following:

ST = 20°C
p0 = 0.40Ω
Δρ = 0.673Ω - 0.40Ω = 0.273Ω (change of resistance)
α = 0.0062 (Temperature Coefficient of Resistance for Ni200)
ΔT = 20°C + 0.273 / (0.0062 * 0.40) = 130°C / 266°F

So, this mod thinks that a 0.273Ω rise on a 0.40Ω coil means that coil is now at 213°F.

But the coil is not Ni200, it's Titanium. The calculation it needed to do was as follows:

ST = 20°C
p0 = 0.40Ω
Δρ = 0.673Ω - 0.40Ω = 0.273Ω (change of resistance)
α = 0.0035 (Temperature Coefficient of Resistance for Titanium)
ΔT = 20°C + 0.273 / (0.0035 * 0.40) = 215°C / 419°F

So this coil that started at 0.40Ω and increased to 0.673Ω has actually heated from 20°C (68°F) to 215°C (419°F).

But because the mod used Ni200's TCR it thinks it's only at 130°C / 266°F.

So setting the temp limiting on any (Ni200-expecting) TC mod to 130°C / 266°F will cause it to back off wattage when the coil is actually at 215°C / 419°F - an offset of 85°C / 153°F

However, this is noticeably different to the real-world offsets used by @tchavei and others. They appear to be setting their TC much higher than the numbers suggest:

For me, my best vape for liquid x is 185C (365f) and for liquid y it's 180C (356f).

I don't really care that in reality the coil is being heated to 230C (446f) or 225C (437f)

So Tony is setting 185°C / 356°F when he wants 230°C / 446°F - an offset of only 45°C / 90°F.

Here's what happens when I put this offset into the TCR calculator.

In the following outputs, values I enter are in bold; values returned by the calc are in red.

TCR, for Ni200: 0.0062
Starting resistance (for an example Ti coil): 0.40Ω
Original temperature: 20°C
Final temperature: 185°C
Ending resistance: 0.8092Ω

TCR, for Titanium: 0.0035
Starting resistance (for an example Ti coil): 0.40Ω
Original temperature: 20°C
Final temperature: 230°C
Ending resistance: 0.694Ω

In other words: The mod is expecting a coil of 0.40Ω to rise to a resistance of 0.8092Ω for the configured temperature of 185°C.

However, a 0.40Ω Titanium coil will reach the desired target temp (230°C) at a resistance of only 0.694Ω.

What temperature is that Titanium coil when it actually reaches 0.8092Ω?

TCR, for Titanium: 0.0035
Starting resistance (for an example Ti coil): 0.40Ω
Original temperature: 20°C
Final temperature: 312.28 °C
Ending resistance: 0.8092Ω

What setting, according to the calc, would be the right temp setting for a Ni200 TC mod when using TC?

TCR, for Ni200: 0.0062
Starting resistance (for an example Ti coil): 0.40Ω
Original temperature: 20°C
Final temperature: 138.54 °C (281 °F)
Ending resistance: 0.694Ω

Therefore, based purely on the numbers, if you want to reach a target temp of 230 °C / 446 °F with Titanium, you should set your normal Ni200 TC mod to 138.54 °C / 281 °F.

But now I cannot immediately reconcile this with the actual practices and experiences of people like @tchavei - they appear to be setting the temp far too high, but are also getting a good experience.

@tchavei you must have done dry burn cotton tests with your offsets? A cotton burn test with the mod set to 330°F (90°F offset from 420°F)?

I don't think I've messed up the calcs as I've been doing them regularly for a week now - though it's still possible I've missed something. What's more possible is that there's more to it than just calculating the final resistance at the target temperature.

Or maybe most Ni200 mods are not using 0.0062 as their TCR (the figure of 0.0062 comes from Dicodes, who recommend it as the value for Ni200; other sources quote 0.006 for pure Nickel.)

If for example most TC mods use 0.005 as the TCR - which I have seen listed one place as the TCR for Ni200, but only one - then the correct temp for 230°C / 446°F would be 166°C / 330°F - still lower than Tony has, but close enough to the ballpark to not really notice.

Of course another possibility is just that, as the Titanium veterans set their offset by experimentation, they might have found a value that works in general usage but is not the most accurate - though if they have done dry burn cotton tests, as surely they must have, it's surprising if those higher settings are not burning cotton.

So maybe it really is that the TCR used by most current TC mods is lower than Dicodes say it should be.

I was planning to put out a new version of my Nickel Purity / Static Resistance calculator specifically for giving the right temperature to use when vaping Titanium (or Resistherm NiFe30) on a Ni200 TC mod.

But there's no point doing that until I know if the figures are real-world usable.

I will do some tests myself today, cotton dry burn tests, but I'd love to hear the thoughts and findings of @tchavei and other TC Titanium veterans!
 
Last edited:

Rossum

Eleutheromaniac
Supporting Member
ECF Veteran
Verified Member
Dec 14, 2013
16,081
105,232
SE PA
@TheBloke

Your're assuming that TCR doesn't vary with temperature, and that Evolv does their calculations in the linear manner your equations describe. I don't think that's a safe assumption. We know that a DNA40 (unlike some of the Chinese mods) produces reasonably accurate temperatures using the nickel wire it's calibrated for. But we also know it produces practically zero vapor if run with a titanium coil and set to 280F, and that it doesn't scorch a dry cellulose wick when set to 330F. Hence I suspect that that the linear model you (and some of the new mods that are becoming available) are using is an over-simplification of what's going on in the real world.
 

TheBloke

Ultra Member
Verified Member
Mar 30, 2015
2,800
3,549
45
Brighton, UK
@Rossum - Thanks for the response.

My understanding (eg from Dicodes) was that while the TCR does slightly vary with temperature (it's a curve), in reality this doesn't make much discernible difference; the curve, while it may be there, is very slight. They stated this in their Application Note for Temp Controlled Vaping.

It's interesting that you get almost no vapour at 280°F, because I most definitely do on my IPV4 (Yihi SX330v4) for example - another mod that's been tested and confirmed very accurate. I don't have a genuine DNA 40 to test on, only clones - which I agree may not be as sophisticated as the original. I do think the Yihi is an equally good benchmark for accurate temp sensing at the target, albeit no doubt using a somewhat different algorithm.

In any case if you're getting no scorched cotton at 330°F that does answer my question.

I'll do some more testing of my own as well. Right now I'm vaping a Resistherm coil on my IPV4, set to 250°F (slightly lower than I suggested for Ti because the TCR is 0.0032 vs 35) intended to represent 420°F and getting lots of vapour and no dry/burnt hits now I've drained the tank.

I do think you're spot on in pointing out that these devices achieve their stated goal in a different way. It may be that the Evolv chip is more sophisticated, at least versus its direct clones, and perhaps that's changing the required behaviour on genuine devices.

I suppose I really should get a genuine one of these days, if only so I can know I'm comparing apples to apples when discussing these things with people :) Maybe I'll get a chip and put one in my Waidea VF flask.

Anyway thanks for the response, I will continue my own tests as well.
 
Last edited:
Status
Not open for further replies.

Users who are viewing this thread