Titanium wire, vaping and safety

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jks89

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Woo! Finally made it to the end!

It has definitely gotten a lot more scientific at the end here! I've been using Ti for about a week or so now, specifically the Spider Silk wire that's been mentioned a couple times. Got it going well in my Delta II rba, but have some work to do now that I recently got a Zephyrus (similar rba deck to Goblin/Goliath). It's pretty tight in there! I managed to fit 2x 9 spaced wrap 26g Ti1 2mm ID, wicked with OCC since I'm out of rayon currently. Came out to .16 and set to 350F @ 35W.

I'm thinking I might go for some 28 or 30g

I definitely have a bit of work to do on my dual coil builds, this is the first time I've tried. (Well, I tried twice last night, so technically the third time I've tried). I'm getting some mixed results (not all the time, but sometimes an inconsistent vape in terms of heat/vapor production), but I think it's due to my coils not firing identically. I did a little bit of pulsing, and one went full yellow while the other got a little blue in the center.
 

Dobo

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Thanks to all the good people in this thread (especially theothersteve and tchavei) for converting me to titanium coils.

I've been using them for 2 days on my rDNA40 and the vape quality has increased quite significantly from what I was getting from nickel. I ordered 28 AWG titanium from zivipf (as I live in Europe) and coil them 7 spaced wraps around 3 or 2.5 mm rod for .49 or .42 ohms. The vape when set at 175 Celsius and 15~18 watts in Lemo 2 and 12~14 watts in PhenomenoN Lite is truly phenomenal!

The finished coil is much sturdier in comparison to nickel and can be wicked with a lot of cotton, which I prefer. Also, it is so much easier to re-wick as it doesn't lose its' shape. Another thing I like is that DNA40 boards usually re-calibrate the resistance after some time and if one builds right the difference is never more than .02 both on nickel and titanium; but with titanium this re-calibration doesn't affect the vape characteristics as much as with nickel, because the percentage of change is twice as small with titanium as with nickel.

Thanks again for all the inputs. I love this community!

P.S. Sometimes, watching the 'big' YouTube reviewers saying things that are plain stupid, I wonder, why the hell don't they read the ECF?
 

tchavei

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Thanks, this is exactly what I was looking for. You can still do a dry burn test with titanium in your dna40 with no singe?
Yep. My first tests were exactly that... Virgin dry rayon and working my way up until the wick got yellow (190C) and then backed down 5C ending with 185C which is perfect for my liquid (70%vg). I used another liquid (50/50) and 185c felt too warm so down to 180c and all was good.
@mrmonday thanks for your PM, I was in the process of replying last night when I fell asleep. My first response was to direct you to this thread so glad you're here.

This is what I was going on to say. I think this is good for general discussion, because it raises a point I wanted to discuss with @tchavei and other Titanium veterans:

The basic principle is that TC mods calculate the temperature by monitoring the rise in resistance of the coil. They do this with the following formula:

ΔT = ST + (Δρ / α * ρ0)
Where:
ST : Starting temperature
ΔT : Change of temperature
Δρ : Change of the resistivity
α : Temperature Coefficient of Resistance (TCR)
ρ0 : Original resistivity


The Temperature Coefficient of Resistance (TCR) is the key number. For Ni200, it's around 0.0062. For Titanium, it's 0.0035.

So let's say you start with a Titanium coil reading 0.40Ω. You vape it on a normal TC mod, that is expecting Ni200. The mod sees its resistance is now 0.673Ω. It calculates the following:

ST = 20°C
p0 = 0.40Ω
Δρ = 0.673Ω - 0.40Ω = 0.273Ω (change of resistance)
α = 0.0062 (Temperature Coefficient of Resistance for Ni200)
ΔT = 20°C + 0.273 / (0.0062 * 0.40) = 130°C / 266°F

So, this mod thinks that a 0.273Ω rise on a 0.40Ω coil means that coil is now at 213°F.

But the coil is not Ni200, it's Titanium. The calculation it needed to do was as follows:

ST = 20°C
p0 = 0.40Ω
Δρ = 0.673Ω - 0.40Ω = 0.273Ω (change of resistance)
α = 0.0035 (Temperature Coefficient of Resistance for Titanium)
ΔT = 20°C + 0.273 / (0.0035 * 0.40) = 215°C / 419°F

So this coil that started at 0.40Ω and increased to 0.673Ω has actually heated from 20°C (68°F) to 215°C (419°F).

But because the mod used Ni200's TCR it thinks it's only at 130°C / 266°F.

So setting the temp limiting on any (Ni200-expecting) TC mod to 130°C / 266°F will cause it to back off wattage when the coil is actually at 215°C / 419°F - an offset of 85°C / 153°F

However, this is noticeably different to the real-world offsets used by @tchavei and others. They appear to be setting their TC much higher than the numbers suggest:



So Tony is setting 185°C / 356°F when he wants 230°C / 446°F - an offset of only 45°C / 90°F.

Here's what happens when I put this offset into the TCR calculator.

In the following outputs, values I enter are in bold; values returned by the calc are in red.

TCR, for Ni200: 0.0062
Starting resistance (for an example Ti coil): 0.40Ω
Original temperature: 20°C
Final temperature: 185°C
Ending resistance: 0.8092Ω

TCR, for Titanium: 0.0035
Starting resistance (for an example Ti coil): 0.40Ω
Original temperature: 20°C
Final temperature: 230°C
Ending resistance: 0.694Ω

In other words: The mod is expecting a coil of 0.40Ω to rise to a resistance of 0.8092Ω for the configured temperature of 185°C.

However, a 0.40Ω Titanium coil will reach the desired target temp (230°C) at a resistance of only 0.694Ω.

What temperature is that Titanium coil when it actually reaches 0.8092Ω?

TCR, for Titanium: 0.0035
Starting resistance (for an example Ti coil): 0.40Ω
Original temperature: 20°C
Final temperature: 312.28 °C
Ending resistance: 0.8092Ω

What setting, according to the calc, would be the right temp setting for a Ni200 TC mod when using TC?

TCR, for Ni200: 0.0062
Starting resistance (for an example Ti coil): 0.40Ω
Original temperature: 20°C
Final temperature: 138.54 °C (281 °F)
Ending resistance: 0.694Ω

Therefore, based purely on the numbers, if you want to reach a target temp of 230 °C / 446 °F with Titanium, you should set your normal Ni200 TC mod to 138.54 °C / 281 °F.

But now I cannot immediately reconcile this with the actual practices and experiences of people like @tchavei - they appear to be setting the temp far too high, but are also getting a good experience.

@tchavei you must have done dry burn cotton tests with your offsets? A cotton burn test with the mod set to 330°F (90°F offset from 420°F)?

I don't think I've messed up the calcs as I've been doing them regularly for a week now - though it's still possible I've missed something. What's more possible is that there's more to it than just calculating the final resistance at the target temperature.

Or maybe most Ni200 mods are not using 0.0062 as their TCR (the figure of 0.0062 comes from Dicodes, who recommend it as the value for Ni200; other sources quote 0.006 for pure Nickel.)

If for example most TC mods use 0.005 as the TCR - which I have seen listed one place as the TCR for Ni200, but only one - then the correct temp for 230°C / 446°F would be 166°C / 330°F - still lower than Tony has, but close enough to the ballpark to not really notice.

Of course another possibility is just that, as the Titanium veterans set their offset by experimentation, they might have found a value that works in general usage but is not the most accurate - though if they have done dry burn cotton tests, as surely they must have, it's surprising if those higher settings are not burning cotton.

So maybe it really is that the TCR used by most current TC mods is lower than Dicodes say it should be.

I was planning to put out a new version of my Nickel Purity / Static Resistance calculator specifically for giving the right temperature to use when vaping Titanium (or Resistherm NiFe30) on a Ni200 TC mod.

But there's no point doing that until I know if the figures are real-world usable.

I will do some tests myself today, cotton dry burn tests, but I'd love to hear the thoughts and findings of @tchavei and other TC Titanium veterans!
I'm sure you didn't made a mistake but I'm with Rossum on this one. According to your calcs, at what 'apparent' temperature should water boil with a titanium coil?

I did the soaked water test and I was surprised to find:

Ni 200 = 99C/100C

Titanium = 96-98C

This didn't make sense to me (using linear coefficient, it should be more around 70C) until I considered the existence of a exponential type of TCR. This is the only way I can explain a small difference of 2C at 100C but almost 50C at 185C


Regards
Tony

Sent from my keyboard through my phone or something like that.
 

Rossum

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This didn't make sense to me (using linear coefficient, it should be more around 70C) until I considered the existence of a exponential type of TCR. This is the only way I can explain a small difference of 2C at 100C but almost 50C at 185C
I don't know if I believe it's actually exponential, but I'm sure not convinced that a linear approximation is at all close to reality.

To me personally, it doesn't matter. Adjust temperature to taste, make sure that temperature doesn't burn a dry wick, vape and be happy. :)
 

tchavei

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I don't know if I believe it's actually exponential, but I'm sure not convinced that a linear approximation is at all close to reality.

To me personally, it doesn't matter. Adjust temperature to taste, make sure that temperature doesn't burn a dry wick, vape and be happy. :)
Well 'kind of' exponential. Not perfectly exponential. It definitely isn't linear. When I saw the temperature my Ti coil sat at soaked in water I was like... Hu? What's going on? Almost no difference between ni 200 and Ti at 212F

Regards
Tony

Sent from my keyboard through my phone or something like that.
 

TheBloke

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Well it's certain that it's not linear, however my understanding was that the amount by which it was curved was so slight as to be negligible (at least for TC purposes, ie within the useful range of TC temperatures.)

Then again, I've just re-checked the Dicodes document - one source of that info - and it is making that claim I believe only for Ni200 and their own Resistherm wire.

So the possibility certainly exists that Titanium is less linear. I do not believe it is exponential though, or anything close to it.

I am currently reading a document from 1959 which I hope will tell us exactly one way or the other :)

In the meantime, could you explain how to do the water test? Is it simply to drip the coil in water and fire it, and expect the evaporation of steam to keep the temperature steady at ~100°C for a few seconds?

PS. Tony, what devices have you performed your tests on? DNA 40 original only or others too?
 
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TheBloke

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Right, I have scanned through this document: US Atomic Energy Commission: Temperature Dependence Of Electrical Resistivity of Metals (1959)

They studied "iodide titanium" (amongst others) - I cannot find a huge amount of info on this, but I understand it's what you get when you put Titanium through the following process?

A refining process in which a metal, such as titanium or zirconium, is combined with iodine vapor and then the iodide volatilized and decomposed at high temperatures to yield a pure solid metal.

@druckle ?

They found a TCR ranging from 0.0037 - 0.0039 in their samples, with the variance described as due to impurities in their samples (this was 1959 after all..) The more impure, the higher the TCR. The most pure of them they stated as 99.9% pure.

I therefore believe this correlates to pure Titanium Grade 1 having a coefficient of 0.0035 - ie I think what they tested is equivalent to what we use, albeit in a modified form (iodide) and slightly impure.

This is the graph of the relationship between resistance (microohm-cm) and temperature (°C). There are three lines in the graph, which are for their three separate samples (TCRs 0.0037, 38, 39 as described above).

I added the red box to denote the area of the temperature graph of interest to us (0-300°C)




This is what I believe is meant by a 'curved TCR' - it is curved, but so little within the TC temperature range as to make no practical difference to the measurements.

Now, many questions remain. Firstly, is it fair to use this graph of iodide titanium figures for questions on Titanium Grade 1? I believe the evidence suggests yes - the fact that they use iodide Titanium at all when what they cared about was Titanium itself (see end); the very close TCR with differences explicable by impurities.

Secondly, and most important - so if it's linear, why the results that you have seen in your tests?

This is why I'd love to know what mods you guys have used - Rossum has only described DNA 40, Tony mentioned DNA 40 but hasn't mentioned if others are used.

if you guys are all testing with DNA 40s, it could be specific to the DNA 40. As @Rossum said, we don't know exactly how it handles its temperature ramp-up and it's no doubt different to other devices.

Finally, does all this matter? Probably not to most - if you have a temperature offset and it works on your mod, who cares? But I think it would be nice to find an answer, if only for our own edification - and if we find that it doesn't work exactly the same on all devices it may will help others in future.

Anyway I just find it fun :)

I will continue trying to find more data for Titanium, maybe I can find a more recent study and one that uses pure Titanium, not the iodide.

As an aside, I emailed Evolv this morning to ask what coefficient they use for Ni200. No idea if they will respond, but if they do that might give some more useful data.

I plan to contact Dicodes as well once I have my 2380, as they seem pretty expert on these things - though it's quite possible they have never used Titanium - they had the coefficient value wrong for it in their manual at first, someone on this forum corrected it for them! I forget who. They may at least be able to shed more light on the curves in coefficients in general.


Extract from the abstract of the above mentioned document, supporting the notion that testing with iodide Titanium is representative of Titanium itself:

The purpose of this investigation was to study the temperature dependence of electrical resistivity of thorium and titanium and to determine whether or not the slope of the resistance versus temperature curve of these metals exhibit anomalous discontinuities.
 
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TheBloke

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As an aside, one thing I just learnt from this document that tell us a little more about curves in TC wires (though not Titanium):

Bittel and Gerlach (1) ~ Potter (2)~ and Nilsson (3) have shown that the resistance versus temperature curve for nickel has an abrupt change in slope at the Curie point.

The Curie point of Nickel is 353°C / 667°F. I suspect that's why the Snow Wolf 200 allows TC up to 350°C / 662°F :) (Though it's dumb to take Ni200 beyond 600°F in any case!)
 

druckle

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Right, I have scanned through this document: US Atomic Energy Commission: Temperature Dependence Of Electrical Resistivity of Metals (1959)

They studied "iodide titanium" (amongst others) - I cannot find a huge amount of info on this, but I understand it's what you get when you put Titanium through the following process?

A refining process in which a metal, such as titanium or zirconium, is combined with iodine vapor and then the iodide volatilized and decomposed at high temperatures to yield a pure solid metal.

@druckle ?

They found a TCR ranging from 0.0037 - 0.0039 in their samples, with the variance described as due to impurities in their samples (this was 1959 after all..) The more impure, the higher the TCR. The most pure of them they stated as 99.9% pure.

I therefore believe this correlates to pure Titanium Grade 1 having a coefficient of 0.0035 - ie I think what they tested is equivalent to what we use, albeit in a modified form (iodide) and slightly impure.

This is the graph of the relationship between resistance (microohm-cm) and temperature (°C). There are three lines in the graph, which are for their three separate samples (TCRs 0.0037, 38, 39 as described above).

I added the red box to denote the area of the temperature graph of interest to us (0-300°C)




This is what I believe is meant by a 'curved TCR' - it is curved, but so little within the TC temperature range as to make no practical difference to the measurements.

Now, many questions remain. Firstly, is it fair to use this graph of iodide titanium figures for questions on Titanium Grade 1? I believe the evidence suggests yes - the fact that they use iodide Titanium at all when what they cared about was Titanium itself (see end); the very close TCR with differences explicable by impurities.

Secondly, and most important - so if it's linear, why the results that you have seen in your tests?

This is why I'd love to know what mods you guys have used - Rossum has only described DNA 40, Tony mentioned DNA 40 but hasn't mentioned if others are used.

if you guys are all testing with DNA 40s, it could be specific to the DNA 40. As @Rossum said, we don't know exactly how it handles its temperature ramp-up and it's no doubt different to other devices.

Finally, does all this matter? Probably not to most - if you have a temperature offset and it works on your mod, who cares? But I think it would be nice to find an answer, if only for our own edification - and if we find that it doesn't work exactly the same on all devices it may will help others in future.

Anyway I just find it fun :)

I will continue trying to find more data for Titanium, maybe I can find a more recent study and one that uses pure Titanium, not the iodide.

As an aside, I emailed Evolv this morning to ask what coefficient they use for Ni200. No idea if they will respond, but if they do that might give some more useful data.

I plan to contact Dicodes as well once I have my 2380, as they seem pretty expert on these things - though it's quite possible they have never used Titanium - they had the coefficient value wrong for it in their manual at first, someone on this forum corrected it for them! I forget who. They may at least be able to shed more light on the curves in coefficients in general.


Extract from the abstract of the above mentioned document, supporting the notion that testing with iodide Titanium is representative of Titanium itself:

The purpose of this investigation was to study the temperature dependence of electrical resistivity of thorium and titanium and to determine whether or not the slope of the resistance versus temperature curve of these metals exhibit anomalous discontinuities.
Preparation of titanium by the iodide approach they mentioned is pretty much the way to get the most pure titanium. I don't remember if they mentioned the oxygen content of their samples but oxygen contamination is one of the big differentiating factors between the various commercially pure grades of titanium (Grade 1, Grade 2) Commercially pure Ti also usually has about 0.2% of iron which comes from the steel reaction chambers used in the Kroll Process which is the primary process used to produce titanium industrially. This titanium produced by the iodide process is going to be significantly more pure than our Grade 1 coils stuff even if the data were acquired in the '50's.

I'm pretty sure their temp/resistivity coefficient data are accurate. The nuclear guys took that kind of stuff very seriously back in those days. :( I also think that while the exact slope may vary a little with purity it's not going to be wildly different from the typical grade 1 material we get today.

I can't explain Tony's water tests on titanium coils with the dna 40 but I'm going to go do the test on a sx mini m class and let you know what that says. Back in a few.


Duane
 

druckle

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I just put a .205 ohm titanium coil on an sx mini m class and used ro water I prepare for my salt water aquarium that measures total dissolved solids of 0 . I'm getting 111F...not 212F. I did the test multiple times and the biggest difference was 111 vs 112 degrees.

Either is something strange about the dna 40...or ??
OK....I do have one working dna 40 out of three....I'll check with that.....gimme 5 min.

Duane
 
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TheBloke

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I just put a .205 ohm titanium coil on an sx mini m class and used ro water I prepare for my salt water aquarium that measures total dissolved solids of 0 . I'm getting 111F...not 212F. I did the test multiple times and the biggest difference was 111 vs 112 degrees.

Either is something strange about the dna 40...or ??
OK....I do have one working dna 40 out of three....I'll check with that.....gimme 5 min.

Duane
Well that's interesting.. and doesn't match anything :)

According to the calcs:
  • A 0.205Ω Titanium coil (0.0035) heated from 20°C (68°F) to 100°C will reach a resistance of 0.2624Ω
  • Calculating that same coil from 0.205Ω -> 0.2624Ω with a coefficient of 0.006 gives a temp of 66°C / 150°F
Where you got 112°F / 44°C

Firstly, can you measure your room temp? Is it near enough 68°F? And were the mod and coil/atty both at room temp when you started (for both tests if you used same coil twice?) And you locked resistance on the yihi first of course?

So we have the Yihi seemingly going way low, and the DNA 40 going way high

According to the numbers alone, that 0.205Ω TI coil when calculated with Ni200's TCR should display 66°C / 150°F.

Compared to 44°C you got on Yihi and 90°C on the DNA 40 - that's almost exactly half way between them in fact :D Half way point from 44->90 is 67°C!

How weird. Don't worry. Somewhere... the truth is out there! :D Maybe vape half your coil on the DNA 40 and half on the Yihi and they'll meet in the middle? :D

I need to go mix some juice as I'm nearly out but I'll do this famous water coil test myself a little later on my IPV4 and DNA 40 clones.

Can someone please verify that all I have to do is dunk the coil in water - or rather, drip water on it - then fire and check the displayed temp? Oh crap, so I can't even do that on the IPV4 because it doesn't display live temp. Grr! I suppose all I can do is progressivley increase the temp until it appears to boil?
 
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druckle

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As an aside, one thing I just learnt from this document that tell us a little more about curves in TC wires (though not Titanium):

Bittel and Gerlach (1) ~ Potter (2)~ and Nilsson (3) have shown that the resistance versus temperature curve for nickel has an abrupt change in slope at the Curie point.

The Curie point of Nickel is 353°C / 667°F. I suspect that's why the Snow Wolf 200 allows TC up to 350°C / 662°F :) (Though it's dumb to take Ni200 beyond 600°F in any case!)

Yes..thermal expansion coefficient, magnetic properties resistivity....a lot of stuff and the neat thing is that the curie temp can be manipulated very nicely with alloying. Hence sophisticated turbine blade tip seals to minimize high temp gas leakage. I had a group many years ago assigned to the task of developing materials of that kind and they did a hell of a job. I think these type alloys are used pretty much by every jet engine manufacturer. We called our alloys Thermalloy xx xy etc. There are likely a ton of different alloy approaches now days to get to the same solution

Duane
 

druckle

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Well that's interesting.. and doesn't match anything :)

According to the calcs:
  • A 0.205Ω Titanium coil (0.0035) heated from 20°C (68°F) to 100°C will reach a resistance of 0.2624Ω
  • Calculating that same coil from 0.205Ω -> 0.2624Ω with a coefficient of 0.006 gives a temp of 66°C / 150°F
Where you got 112°F / 44°C

Firstly, can you measure your room temp? Is it near enough 68°F? And were the mod and coil/atty both at room temp when you started (for both tests if you used same coil twice?) And you locked resistance on the yihi first of course?

So we have the Yihi seemingly going way low, and the DNA 40 going way high

According to the numbers alone, that 0.205Ω TI coil when calculated with Ni200's TCR should display 66°C / 150°F.

Compared to 44°C you got on Yihi and 90°C on the DNA 40 - that's almost exactly half way between them in fact :D Half way point from 44->90 is 67°C!

How weird. Don't worry. Somewhere... the truth is out there! :D Maybe vape half your coil on the DNA 40 and half on the Yihi and they'll meet in the middle? :D

I need to go mix some juice as I'm nearly out but I'll do this famous water coil test myself a little later on my IPV4 and DNA 40 clones.

Can someone please verify that all I have to do is dunk the coil in water - or rather, drip water on it - then fire and check the displayed temp? Oh crap, so I can't even do that on the IPV4 because it doesn't display live temp. Grr! I suppose all I can do is progressivley increase the temp until it appears to boil?
My room temp is 85F/29.4C (It's Arizona and rainy/cloudy today) Hasn't rained in June in Arizona since 1321 AD (kidding)

the temps on the mods and the coil were the same and I did set the yihi initial resistance

There is something definitely strange for both apparently. I didn't check the results vs. your spreadsheet but I seem to remember folks saying to set the temp on a dna 40 around 100F low if one is running titanium. The 111F seemed to fit that...so I left it to The Bloke to do the heavy math lifting. :)

Duane
 
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druckle

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I just duplicated the 111 number on three different sx m class mods. I got a little wider range 110-113. Whatever causes it to read that way must be designed in...and whatever makes DNA 40 read as it does must be designed in since one in Portugal and one in Arizona are sort of in synch.

Duane
 
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